发明申请
- 专利标题: Bromide reduction process in liquid solutions
- 专利标题(中): 液体溶液中的溴化物还原过程
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申请号: US10999817申请日: 2004-11-30
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公开(公告)号: US20060110312A1公开(公告)日: 2006-05-25
- 发明人: Gerald Ziegenbalg , Harald Liebe , Murray Schultz
- 申请人: Gerald Ziegenbalg , Harald Liebe , Murray Schultz
- 优先权: CA2,488,180 20041123
- 主分类号: C01B11/20
- IPC分类号: C01B11/20
摘要:
The invention provides a method for reducing bromine levels in brine solutions such as potassium chloride brine solutions. Bromide in solution is converted to hypobromite by the addition of an oxidant such as sodium hypochlorite. Hypobromite is precipitated by the addition of a metal cation such as magnesium under conditions of basic pH. The process is pH dependent such that the most efficient removal of bromine is achieved at a sodium hydroxide concentration of 90-200 mM. The pH optimum is also temperature dependent such that increased temperature lowers the optimal pH for bromide removal. The invention further provides a bromine-reduced potassium chloride product, suitable for uses in industrial applications. By the method of the invention bromine levels in a potassium chloride feed stock can be reduced by 97% or more.
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