A lithium secondary battery employing as its negative electrode active material a material that increases in volume by alloying with lithium during charge achieves high discharge capacity and good cycle performance. The lithium secondary battery includes a negative electrode having a negative electrode active material (2) and a negative electrode current collector, a positive electrode having a positive electrode active material (1) and a positive electrode current collector (3), and a non-aqueous electrolyte. The negative electrode active material (2) is a material that increases in volume by alloying with lithium during charge. The negative electrode active material (1) is arranged so as to be on, and in contact with, the negative electrode current collector. The negative electrode active material (2) contains, when in an end-of-discharge condition, 8% or more of lithium with respect to the total capacity of the negative electrode active material (2) as measured when it does not contain lithium.