Briefly in accordance with one embodiment, the present technique provides a liquid core waveguide photon energy material processing system. The system includes a photon energy source configured to generate a high intensity photon beam for material processing. The system also includes a liquid core waveguide configured to transmit the high intensity photon beam towards at least one object for material processing. The liquid core waveguide in-turn includes a liquid core having a first refractive index and a cladding element having a second refractive index and configured to guide the liquid core, wherein the first refractive index is higher than the second refractive index. The system further includes a liquid source configured to generate the liquid core. The liquid core includes a liquid solution.