发明申请
- 专利标题: Polyorganosilsesquioxane supported metallocene catalysts
- 专利标题(中): 聚有机倍半硅氧烷负载金属茂催化剂
-
申请号: US10765688申请日: 2004-01-27
-
公开(公告)号: US20060154809A1公开(公告)日: 2006-07-13
- 发明人: David Rauscher , William Gauthier
- 申请人: David Rauscher , William Gauthier
- 主分类号: B01J31/00
- IPC分类号: B01J31/00 ; C08F4/44
摘要:
Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to produce syndiotactic polypropylene or isotactic polypropylene. The supported catalyst comprises a stereospecific metallocene catalyst component and a co-catalyst component comprising an alkylalumoxane. Both the metallocene catalyst component and the co-catalyst component are supported on a particulate polyorganosilsesquioxane support comprising spheroidal particles of a polyorganosilsesquioxane having an average. diameter with the range of 0.3-20 microns. The polyorganosilsesquioxane support is characterized by relatively low surface area, specifically a surface area less than 100 square meters per gram. The metallocene component can take the form of a single metallocene or two or more metallocenes which are co-supported on the polyorganosilsesquioxane support.
公开/授权文献
- US07125937B2 Polyorganosilsesquioxane supported metallocene catalysts 公开/授权日:2006-10-24
信息查询