发明申请
US20060161010A1 Process for the epoxidation of an olefin with improved energy balance
审中-公开
具有改善的能量平衡的烯烃的环氧化方法
- 专利标题: Process for the epoxidation of an olefin with improved energy balance
- 专利标题(中): 具有改善的能量平衡的烯烃的环氧化方法
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申请号: US11036051申请日: 2005-01-18
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公开(公告)号: US20060161010A1公开(公告)日: 2006-07-20
- 发明人: Hans-Georg Gobbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
- 申请人: Hans-Georg Gobbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
- 申请人地址: DE Ludwigshafen US MI Midland
- 专利权人: BASF Aktiengesellschaft,The Dow Chemical Company
- 当前专利权人: BASF Aktiengesellschaft,The Dow Chemical Company
- 当前专利权人地址: DE Ludwigshafen US MI Midland
- 主分类号: C07D301/12
- IPC分类号: C07D301/12
摘要:
The invention relates to a process for the epoxidation of an olefin comprising (a) reacting the olefin with hydrogen peroxide in the presence of methanol as solvent in at least two reaction stages to obtain a mixture (M-a) comprising olefin oxide, unreacted olefin, methanol and water, wherein between at least two reaction stages, olefin oxide is separated by distillation; (b) separating unreacted olefin from the mixture (M-a) by distillation to obtain a mixture (M-bi) comprising at least 80 wt.-% of olefin and a mixture (M-bii) comprising methanol, water and at least 7 wt.-% of olefin oxide; (c) separating olefin oxide from the mixture (M-bii) in at least one distillation stage to obtain a mixture (M-ci) comprising at least 99 wt.-% of oletin oxide and a mixture (M-cii) comprising water and at least 55 wt.-% of methanol; (d) separating methanol from the mixture (M-cii) in at least one distillation stage to obtain a mixture (M-di) comprising at least 85 wt.-% of methanol and up to 10 wt.-% of water, and a mixture (M-dii) comprising at least 90 wt.-% of water; wherein a vapor top stream (Td) obtained from at least one distillation column used in (d), said vapor top stream (Td) comprising at least 85 wt.-% methanol, is used to operate at least partially at least one vaporizer used in at least one distillation column used in at least one of stages (a), (b) and (c).
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