发明申请
- 专利标题: Process for the conversion of heavy feedstocks such as heavy crude oils and distillation residues
- 专利标题(中): 用于转化重质原料如重质原油和蒸馏残余物的方法
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申请号: US10539058申请日: 2003-12-12
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公开(公告)号: US20060163115A1公开(公告)日: 2006-07-27
- 发明人: Romolo Montanari , Mario Marchionna , Nicoletta Panariti , Alberto Delbianco , Sergio Rosi
- 申请人: Romolo Montanari , Mario Marchionna , Nicoletta Panariti , Alberto Delbianco , Sergio Rosi
- 申请人地址: IT ROME IT SAN DONATO MILANESE IT SAN DONATO MILANESE
- 专利权人: ENI S.P.A.,SNAMPROGETTI S.P.A.,ENITECNOLGIE S.P.A.
- 当前专利权人: ENI S.P.A.,SNAMPROGETTI S.P.A.,ENITECNOLGIE S.P.A.
- 当前专利权人地址: IT ROME IT SAN DONATO MILANESE IT SAN DONATO MILANESE
- 优先权: ITMI2002A002713 20021220; ITMI2003A000693 20030408
- 国际申请: PCT/EP03/14544 WO 20031212
- 主分类号: C10G65/02
- IPC分类号: C10G65/02
摘要:
Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues, heavy oils coming from catalytic treatment, thermal tars, oil sand bitumens, various kinds of coals and other high-boiling feedstocks of a hydrocarbon origin known as black oils, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), comprising the following steps: • mixing at least part of the heavy feedstock and/or at least most of the stream containing asphaltenes obtained in the deasphalting unit with a suitable hydrogenation catalyst and sending the mixture obtained to a hydrotreatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; • sending the stream containing the hydrotreatment reaction product and the catalyst in dispersed phase to one or more distillation or flash steps (D) whereby the different fractions coming from the hydrotreatment reaction are separated; • recycling at least part of the distillation residue (tar) or liquid leaving the flash unit, containing the catalyst in dispersed phase, rich in metal sulfides produced by demetallation of the feedstock and possibly coke, to the deasphalting zone (SDA) in the presence of solvents, optionally also fed with at least a fraction of the heavy feedstock, obtaining two streams, one consisting of deasphalted oil (DAO) and the other containing asphaltenes, characterized in that a fraction of the stream containing as phaltenes, coming from the deasphalting section (SDA), called flushing stream, is sent to a treatment section with a suitable solvent for the separation of the product into a solid fraction and a liquid fraction from which said solvent can be subsequently removed.
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