发明申请
- 专利标题: Two-stage method for producing butane diol with intermediated separation of succinic anhydride
- 专利标题(中): 制备丁二酸酐中间分离丁二醇的两阶段方法
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申请号: US10516922申请日: 2003-06-11
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公开(公告)号: US20060167323A1公开(公告)日: 2006-07-27
- 发明人: Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rosch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
- 申请人: Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rosch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
- 优先权: DE10225929.1 20020611
- 国际申请: PCT/EP03/06100 WO 20030611
- 主分类号: C07C31/18
- IPC分类号: C07C31/18
摘要:
The present invention relates to a process for preparing optionally alkyl-substituted 1,4-butanediol by two-stage catalytic hydrogenation in the gas phase of C4-dicarboxylic acids and/or of derivatives thereof having the following steps: a) introducing a gas stream of a C4-dicarboxylic acid or of a derivative thereof at from 200 to 300° C. and from 2 to 60 bar into a first reactor and catalytically hydrogenating it in the gas phase to a product which contains mainly optionally alkyl-substituted γ-butyrolactone; b) removing succinic anhydride from the product obtained in step a), preferably to a residual level of from
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