A fabric care composition and process for using the composition to treat fabrics are provided. The fabric care composition comprises a sucrose ester, a cationic polysaccharide and a dispersing medium, wherein the charge density of the cationic polysaccharide is from about 0.05 to about 5.5 meq/gram. Optionally, deposition agents and adjunct materials may also be included. The present compositions are used to treat fabrics to impart one or more of the following benefits tot eh treated fabrics: improved fabric softness, wrinkle reduction after drying, ease of ironing, in-wear shape retention, fabric elasticity, fabric tensile strength, fabric tear strength, and/or color protection.