A pixel structure for a multi-domain vertical alignment liquid crystal display (MVA-LCD) is disclosed. The pixel structure includes a pixel array having a plurality of adjacently arranged sub-pixels; and a first substrate and a second substrate having, respectively, first and second means for controlling tilt angles of liquid crystal molecules between the first and second substrates. The first and second means are alternately disposed to define each of the sub-pixels into a plurality of different azimuthal angle domains. Moreover, each of the sub-pixels also is further defined into at least two different polar angle domains. The azimuthal angle domains and polar angle domains of two adjacent sub-pixels have a mirror-image arrangement.