Provided is a method for adjusting Fast Fourier Transform (FFT) window positioning in a Multi Band Orthogonal Frequency Division Multiplexing Ultra-Wideband (MB-OFDM UWB) system. The method includes the steps of acquiring an initial FFT window position and a frequency hopping position, demodulating a received signal by using the initial FFT window position and the frequency hopping position acquired in the acquiring step, transmitting received data information to a Media Access Control (MAC) layer with a reception frame (RX frame) structure and judging at the MAC layer whether or not a packet error is occurred based on Frame Check Sequences (FCSs), and if no packet error is occurred, returning to the demodulating step, and if the packet error is occurred, changing a register map by using a predetermined interface line in a MAC-physical layer (MAC-PHY) interface to thereby adjust the FFT window position and the frequency hopping position, and then returning to the demodulating step.