发明申请
- 专利标题: Process for producing cycloolefin addition polymer
- 专利标题(中): 制备环烯加成聚合物的方法
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申请号: US10581525申请日: 2004-11-30
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公开(公告)号: US20070155922A1公开(公告)日: 2007-07-05
- 发明人: Satoshi Ebata , Michitaka Kaizu , Noboru Oshima
- 申请人: Satoshi Ebata , Michitaka Kaizu , Noboru Oshima
- 申请人地址: JP Tokyo 104-8410
- 专利权人: JSR Corporation
- 当前专利权人: JSR Corporation
- 当前专利权人地址: JP Tokyo 104-8410
- 优先权: JP2003-407558 20031205
- 国际申请: PCT/JP04/17813 WO 20041130
- 主分类号: C08F4/80
- IPC分类号: C08F4/80
摘要:
[Means to solve problems] The process for preparing a cycloolefin addition polymer comprises addition-polymerizing monomers containing a specific cycloolefin compound in the presence of ethylene and a multicomponent catalyst containing, as essential components, (a) a palladium compound, (b) a compound selected from an ionic boron compound, an ionic aluminum compound, a Lewis acidic aluminum compound and a Lewis acidic boron compound and (c) a specific phosphine compound or its phosphonium salt. [Effect] A cycloolefin compound is addition-polymerized using a specific palladium catalyst and using ethylene as a molecular weight modifier, whereby a cycloolefin addition polymer having a molecular weight preferable for a sheet or a film used for an optical material can be prepared using small amounts of the molecular weight modifier and the palladium catalyst.
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