A liquid-gas separator for a direct liquid feed fuel cell includes: a housing having an open hole; a gas extracting membrane that covers the open hole and transmits only the gas; a liquid extracting member that defines a first chamber that contacts the gas extracting membrane and a second chamber that does not contact the gas extracting membrane, and selectively transmits the liquid in the first chamber to the second chamber; an inlet that guides the liquid and the gas into the housing; and an outlet that is connected to the second chamber and guides the liquid in the second chamber to the outside.