发明申请
- 专利标题: Process for carbonylation of alkyl ethers
- 专利标题(中): 烷基醚羰基化方法
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申请号: US11639420申请日: 2006-12-15
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公开(公告)号: US20070238897A1公开(公告)日: 2007-10-11
- 发明人: Patricia Cheung , Enrique Iglesia , John Sunley , David Law , Aditya Bhan
- 申请人: Patricia Cheung , Enrique Iglesia , John Sunley , David Law , Aditya Bhan
- 申请人地址: US CA Oakland GB Middlesex
- 专利权人: The Regents of the University of California,BP Chemicals Ltd.
- 当前专利权人: The Regents of the University of California,BP Chemicals Ltd.
- 当前专利权人地址: US CA Oakland GB Middlesex
- 主分类号: C07C67/00
- IPC分类号: C07C67/00
摘要:
A product comprising a lower alkyl ester of a lower aliphatic carboxylic acid is produced by a process comprising reacting under substantially anhydrous conditions a lower alkyl ether with carbon monoxide in the presence of a zeolite catalyst having an 8-member ring channel which is interconnected with a channel defined by a ring with greater than or equal to 8 members, the 8-member ring having a window size of at least 2.5 Angstroms×at least 3.6 Angstroms and at least one Brønsted acid site and the zeolite having a silica:X2O3 ratio of at least 5, wherein X is selected from aluminum, boron, iron, gallium and mixtures thereof.
公开/授权文献
- US07465822B2 Process for carbonylation of alkyl ethers 公开/授权日:2008-12-16