发明申请
- 专利标题: Polycarbonates made using highly selective catalysts
- 专利标题(中): 使用高选择性催化剂制备的聚碳酸酯
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申请号: US11812106申请日: 2007-06-15
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公开(公告)号: US20070255039A1公开(公告)日: 2007-11-01
- 发明人: Geoffrey Coates , Zengquan Qin , Claire Cohen
- 申请人: Geoffrey Coates , Zengquan Qin , Claire Cohen
- 申请人地址: US NY Ithaca
- 专利权人: Cornell Research Foundation, Inc.
- 当前专利权人: Cornell Research Foundation, Inc.
- 当前专利权人地址: US NY Ithaca
- 主分类号: B01J31/00
- IPC分类号: B01J31/00 ; C08G67/02
摘要:
Poly(propylene carbonates) are prepared from propylene oxide and CO2 with less than 10% cyclic propylene carbonate by product using cobalt based catalysts of structure preferably in combination with salt cocatalyst, very preferably cocatalyst where the cation is PPN+ and the anion is Cl− or OBzF5−. Novel products include poly(propylene carbonates) having a stereoregularity greater than 90% and/or a regioregularity of greater than 90%.
公开/授权文献
- US07674873B2 Polycarbonates made using highly selective catalysts 公开/授权日:2010-03-09
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