发明申请
- 专利标题: Method for Controlling the Reactor Admission Temperature During the Production of Methylamine
- 专利标题(中): 控制甲胺生产过程中反应器进口温度的方法
-
申请号: US10573185申请日: 2004-09-24
-
公开(公告)号: US20070270614A1公开(公告)日: 2007-11-22
- 发明人: Werner Reutemann , Rolf Wambsganss , Frank Poplow , Theodor Weber , Karl-Heinz Ross , Manfred Julius
- 申请人: Werner Reutemann , Rolf Wambsganss , Frank Poplow , Theodor Weber , Karl-Heinz Ross , Manfred Julius
- 申请人地址: DE Ludwigshafen D-67056
- 专利权人: BASF Aktiengesellschaft Patents, Trademarks and Licenses
- 当前专利权人: BASF Aktiengesellschaft Patents, Trademarks and Licenses
- 当前专利权人地址: DE Ludwigshafen D-67056
- 优先权: DE10344283.9 20030924
- 国际申请: PCT/EP04/10765 WO 20040924
- 主分类号: C07C209/14
- IPC分类号: C07C209/14
摘要:
The invention relates to a process for preparing methylamines by gas-phase reaction of methanol and ammonia as starting materials at a pressure in the range from 15 to 30 bar in the presence of heterogeneous catalyst. The starting materials are vaporized in one or more heat exchangers (1, 2, 3), superheated to produce a feed gas stream and subsequently fed into a reactor (4), with the mixing of the starting materials being able to be carried out in the feed stream to one of the heat exchangers (1, 2, 3) or at any desired position in a heat exchanger (1, 2, 3). A product gas stream comprising monomethylamine, dimethylamine and trimethylamine and also reaction by-products is taken off from the reactor (4). To control the reactor inlet temperature of the starting materials to a temperature in the range from 360° C. to 370° C., all or some of the feed gas stream or the product gas stream is passed through an adjustable valve (5) in order to vary the pressure and thus the condensation temperature.