A composition capable of coating a substrate and curing to provide a hydrophobic film inhibiting corrosion, the composition comprising: (a) a bis-silane comprising between about 0.5 weight percent to about 50 weight percent of the composition; and (b) a water soluble or dispersible polymer comprising between 10 weight percent to about 80 weight percent of the composition. A further exemplary superprimer in accordance with the instant invention includes a composition capable of coating a substrate and curing to provide a hydrophobic film inhibiting corrosion, the composition comprising: (a) a mixture of silanes; (b) a dispersible or soluble resin; and (c) an aqueous or non-aqueous solvent. Moreover, the invention includes the aforementioned superprimer composition, wherein the mixture of silanes includes at least one of a bis-sulfur silane, a bis-benzene silane, a bis-alkane silane, a bis-alkene silane, and a bis-amino silane.