发明申请
US20080125554A1 METHODS OF PRODUCING WATER-SOLUBLE, NON-TURBID COPOLYMERS OF AT LEAST ONE WATER-SOLUBLE N-VINYLLACTAM AND AT LEAST ONE HYDROPHOBIC COMONOMER
有权
生产水溶性方法,至少一种水溶性N-乙烯基甲酰胺和至少一种疏水性共聚物的非涡轮共聚物
- 专利标题: METHODS OF PRODUCING WATER-SOLUBLE, NON-TURBID COPOLYMERS OF AT LEAST ONE WATER-SOLUBLE N-VINYLLACTAM AND AT LEAST ONE HYDROPHOBIC COMONOMER
- 专利标题(中): 生产水溶性方法,至少一种水溶性N-乙烯基甲酰胺和至少一种疏水性共聚物的非涡轮共聚物
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申请号: US11947223申请日: 2007-11-29
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公开(公告)号: US20080125554A1公开(公告)日: 2008-05-29
- 发明人: Rainer Dobrawa , Ralf Widmaier , Klaus Schnell , Karl-Hermann Strube , Jurgen Nieberle , Reinhold Dieing , Bernd de Potzolli , Andreas Gruber , Ulrich Filges , Martin Meister , Josef Neutzner , Wolfgang Bouquet , Eberhard Schupp
- 申请人: Rainer Dobrawa , Ralf Widmaier , Klaus Schnell , Karl-Hermann Strube , Jurgen Nieberle , Reinhold Dieing , Bernd de Potzolli , Andreas Gruber , Ulrich Filges , Martin Meister , Josef Neutzner , Wolfgang Bouquet , Eberhard Schupp
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DE Ludwigshafen
- 优先权: EP06124999.1 20061129
- 主分类号: C08F4/36
- IPC分类号: C08F4/36
摘要:
Methods of producing vinyllactam copolymers which include: providing at least one water-soluble N-vinyllactam; providing at least one hydrophobic comonomer; and subjecting the at least one water-soluble N-vinyllactam and the at least one hydrophobic comonomer to free-radical polymerization in an organic solvent in the presence of an initiator, under a combination of process measures selected from the group consisting of A and B; wherein:(A) comprises (i) polymerization under reflux, and at least two of (ii), (iii), (iv), (v), (vi), and (vii), wherein (ii) comprises an addition of at least 5 mol % of N-vinyllactam to the polymerization mixture if at least 70 mol % of the total amount of hydrophobic monomer used have completely reacted, (iii) comprises return of condensate formed in the reflux from below to the polymerization mixture, (iv) comprises introduction of the initiator in the form of a solution in an organic solvent from below into the polymerization mixture, (v) comprises addition of N-vinyllactam to the reflux, (vi) comprises distilling off a portion of the organic solvent and continuing the polymerization following conversion of 70 to 99% by weight of the N-vinyllactam used, and (vii) comprises introduction of at least one monomer from below into the polymerization mixture; and wherein(B) comprises (viii) polymerization under a superatmospheric pressure such that vaporization of the polymerization components is avoided, and at least one of (i), (ii), (iii), (iv), (v), (vi), and (vii), with the proviso that a combination of (viii) with any of (i), (iii) or (v) is carried out sequentially.
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