- 专利标题: N-Substituted Imides As Polymerization Initiators
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申请号: US11666887申请日: 2005-10-31
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公开(公告)号: US20080132600A1公开(公告)日: 2008-06-05
- 发明人: Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
- 申请人: Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
- 优先权: EP04105620.1 20041109
- 国际申请: PCT/EP05/55646 WO 20051031
- 主分类号: C08L79/08
- IPC分类号: C08L79/08 ; C07D209/48 ; C07D221/06 ; C07D207/46 ; C07D209/56
摘要:
The invention relates to novel N-substituted imides and polymerizable compositions comprising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent —CO—N—CO— group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy-carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5-6 membered ring, optionally interrupted by —NH—, —N(C1-C8alkyl)-, —O- and/or S-atoms.
公开/授权文献
- US07723399B2 N-substituted imides as polymerization initiators 公开/授权日:2010-05-25