A method and system for processing a call change request in an IMS are provided, in which a network entity receives a call request message requesting a first call from a calling UE, stores call information and caller information of the call request message, forwards the call request message to a called UE, acquires, upon receipt of a call change request message requesting change of the first call to a second call from the called UE during the first call, the caller information of the calling UE using an old call information included in the call change request message and the stored call information, inserts the caller information in receiver information of the call change request message, delivers the call change request message to the calling UE, and establishes the second call between the calling UE and the called UE by replacing the first call with the second call.