The present invention is directed to a method for producing white light. The method includes applying a voltage to an organic light emitting device including a light emissive layer directly adjacent to a layer comprising at least one small molecule material capable of hole blocking and electron transport, the light emissive layer including at least one blue light emissive polymer, where the at least one small molecule material and the at least one blue light emissive polymer form a light emissive exciplex at or near an interface of the light emissive layer and the layer including the at least one small molecule material.