The present invention relates to a tag anti-collision Radio Frequency Identification (RFID) system and a method for tag identification. The method for tag identification consists of a first step of initializing a queue (Q) field and storing a prefix of a candidate queue (CQ) field in the queue field; a second step of transmitting a query including the prefix stored in the queue field to the RFID tags, and deleting the transmitted prefix from the queue field; a third step of inserting a prefix, in which prefixes 0 and 1 are inserted into a rear portion of a prefix of a previously transmitted query, into the queue field if two or more tags respond to the previously transmitted prefix and, therefore, the tags cannot be identified, and inserting the prefix of the previously transmitted query into the candidate queue field and deleting an unnecessary prefix stored in the candidate queue if there is no response or only one tag responds with respect to the previously transmitted prefix; and a fourth step of determining whether a prefix stored in the queue field exists, and returning to the second step if there is a prefix stored in the queue field.