发明申请
- 专利标题: Method for the Recovery of Ruthenium From Used Ruthenium Oxide-Containing Catalysts
- 专利标题(中): 从使用的含氧化钌催化剂中回收钌的方法
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申请号: US12158085申请日: 2006-12-21
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公开(公告)号: US20080293836A1公开(公告)日: 2008-11-27
- 发明人: Olga Schubert , Heiko Urtel , Michael Hesse , Martin Sesing , Claus Hofmann , Iris Kristalis
- 申请人: Olga Schubert , Heiko Urtel , Michael Hesse , Martin Sesing , Claus Hofmann , Iris Kristalis
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 优先权: DE102005061954.1 20051223
- 国际申请: PCT/EP06/70059 WO 20061221
- 主分类号: C07C27/00
- IPC分类号: C07C27/00
摘要:
The invention relates to a process for recovering ruthenium from a used ruthenium-comprising catalyst which comprises ruthenium as ruthenium oxide on a support material which is sparingly soluble in mineral acid, which comprises the steps: a) the catalyst comprising ruthenium oxide is treated in a stream of hydrogen, with ruthenium oxide present on the support being reduced to metallic ruthenium; b) the reduced catalyst from step a) comprising metallic ruthenium on the support material is treated with hydrochloric acid in the presence of an oxygen-comprising gas, with the metallic ruthenium present on the support being dissolved as ruthenium(III) chloride and being obtained as ruthenium(III) chloride solution; c) if appropriate, the ruthenium(III) chloride solution from step b) is worked up further.
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