A method for forming a patterned structure within a microelectronic structure uses a non-directly imageable organic material layer located over a substrate and a directly imageable inorganic material layer located upon the non-directly imageable organic material layer. The directly imageable inorganic material layer is directly imaged to form a patterned inorganic material layer. The patterned inorganic material layer is used as a first etch mask within a first etch method that etches the non-directly imageable organic material layer to form a patterned organic material layer. At least the patterned organic material layer is used as a second etch mask within a second etch method that etches the substrate to form a patterned structure within the substrate.