发明申请
- 专利标题: Ion-Dissociative Functional Compound, Method for Production Thereof, Ionic Conductor, and Electrochemical Device
- 专利标题(中): 离子解离功能化合物,其生产方法,离子导体和电化学装置
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申请号: US10567283申请日: 2004-08-04
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公开(公告)号: US20090004525A1公开(公告)日: 2009-01-01
- 发明人: Kazuaki Fukushima , Shuichi Takizawa , Koichiro Hinokuma , Atsushi Nishimoto , Kazuhiro Noda
- 申请人: Kazuaki Fukushima , Shuichi Takizawa , Koichiro Hinokuma , Atsushi Nishimoto , Kazuhiro Noda
- 优先权: JP2003-286228 20030804; JP2003-361440 20031022
- 国际申请: PCT/JP04/11528 WO 20040804
- 主分类号: H01M8/10
- IPC分类号: H01M8/10 ; C07C309/23 ; C07C311/10
摘要:
Disclosed herein are an ion-dissociative functional compound, a method for production thereof, an ionic conductor, and an electrochemical device, the ion-dissociative functional compound being thermally and chemically stable under the condition required of fuel cells and being suitable for use as a material such as protonic conductor in fuel cells.The proton-dissociative functional compound shown in FIG. 1A is composed of a fullerene C60 molecule and about 10 sulfonic acid groups —SO3H as proton-dissociative groups each attached to the fullerene through a difluoromethane group —CF2—. The proton-dissociative functional compound shown in FIG. 1B is composed of fullerene molecules three-dimensionally connected to each other through a linking group —CF2SO2NHSO2CF2—. It contains, as the proton-dissociative group, sulfoneimide groups —SO2NHSO2— and sulfoneamide groups —SO2H2 in addition to sulfonic acid groups. These compounds are prepared by introduction of difluoro(fluorosulfonyl)methyl groups into fullerene molecules, and ensuing imidization and hydrolysis.