A guiding device for a synchronous connector comprises a strip-like synchronous connector and at least one connecting member. Both ends of the synchronous connector are formed with two opposite fixing seats. The connecting member with elastic deformation characteristic is serially connected and fixed in the fixing seats at both ends of the synchronous connector, slide correspondingly to the clearance change during the operation of the two ends of the synchronous connector, and bend correspondingly to the turning action of the synchronous connector. By such arrangements, the elastic deformation characteristic of the connecting member can be utilized to avoid the collision interference with the rail wall surface, and the linear guiding device will be circulated smoothly and stably. In addition, the guiding device has the effect of absorbing the radial deformation of the synchronous connector and producing sufficient degree of freedom.