The liquid is supplied to an emitter electrode which is provided at a tip of a liquid carrier, receives a high voltage, is electrical-charged, and discharged as a mist of charged minute water particles of nanometer order from the emitter electrode. The emitter electrode discharges the mist of the charged minute water particles of micron order at the same time by a pressure which is applied to the liquid which is supplied to the tip of the emitter electrode. An electrostatically atomizing device supplies liquid to an emitter electrode of a tip of a liquid carrier, applies the high voltage to the liquid, electrically-charges the liquid, and causes the emitter electrode to discharge a mist of charged minute water particles of nanometer order. In addition, the electrostatically atomizing device applies a pressure to the emitter electrode and causes the emitter electrode to discharge a mist of the charged minute water particles of micron order. The electrostatically atomizing device is able to humidify a space by the mist of the charged minute water particles of micron order as well as is able to decompose harmful substances in the space, is able to sterilize and deodorize the substances in the space by radicals which is included by the mist of the charged minute water particles of nanometer order.