发明申请
- 专利标题: Method of preparing cathode containing Iron disulfide for a lithium cell
- 专利标题(中): 制备锂电池用二硫化铁的阴极的方法
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申请号: US12154572申请日: 2008-05-23
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公开(公告)号: US20090291366A1公开(公告)日: 2009-11-26
- 发明人: Maya Stevanovic , Michael Pozin , Yelena Kouznetsova , Steven J. Specht , Fred J. Berkowitz
- 申请人: Maya Stevanovic , Michael Pozin , Yelena Kouznetsova , Steven J. Specht , Fred J. Berkowitz
- 主分类号: H01M4/40
- IPC分类号: H01M4/40 ; H01M4/08
摘要:
A primary cell having an anode comprising lithium or lithium alloy and a cathode comprising iron disulfide (FeS2) or a mixture of iron disulfide (FeS2) and iron sulfide (FeS) and conductive carbon particles. A cathode slurry is prepared comprising the FeS2 or FeS2 plus FeS powder, conductive carbon, binder, and a solvent. The binder is preferably a styrene-ethylene/butylene-styrene (SEBS) block copolymer. There is an advantage discovered in utilizing a hydronaphthalene solvent to form the cathode slurry. The preferred solvent is 1,2,3,4-tetrahydronaphthalene or decahydronaphthalene and mixtures thereof. The slurry mixture is coated onto a conductive substrate and the solvent evaporated leaving a dry cathode coating on the substrate. Higher drying temperature may be used resulting in a dry cathode coating which resists cracking. The anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added.
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