The present invention relates to a URL providing apparatus and a method thereof, and a mobile station that accesses the Internet by using the provided URL, and an Internet access method thereof. The mobile station attaches an RF-ID tag that stores an RF-ID tag value corresponding to identification information of the mobile station thereto, and thus when a user brings the mobile station into an interrogation range of an RF-ID reader included in the URL providing apparatus, the URL providing apparatus receives the corresponding RF-ID tag value from the RF-ID reader. When the URL providing apparatus acquires an IP address of the mobile station by using the received RF-ID tag value and provides a URL to the mobile station by using the acquired IP address, the mobile station automatically accesses the Internet by using the URL. Such an Internet access method can minimize additional cost of the mobile station and simplify an Internet access process to a specific URL.