An object of the present invention is to provide a multilayer film that can make large the amount of outgoing light from a liquid crystal device such as liquid crystal display element and liquid crystal aberration compensating element and at the same time, can realize a high contract in a liquid crystal display element. The multilayer film of the present invention is a multilayer film which is formed on an inner side of a transparent substrate and contains a transparent electrically-conductive film and an orientation film, in which an antireflection film is provided at least either between the transparent substrate and the transparent electrically-conductive film or between the transparent electrically-conductive film and the orientation film.