A method of producing a multilayer structure including a substrate, an adhesive layer and a metal layer, the method including: forming the adhesive layer on the substrate or a metal foil that forms the metal layer by applying a composition containing an acrylic resin having a repeating unit that is derived from an ethylenic unsaturated monomer having a divalent sulfur atom, and applying energy to the composition; and (if the adhesive layer is formed on the substrate) forming the metal layer on the adhesive layer by laminating a metal foil or forming a metal film by evaporation or sputtering, or (if the adhesive layer is formed on the metal foil) forming an organic resin layer that forms the substrate on the adhesive layer by a casting method.