The invention provides a curable fluoroelastomeric composition comprising: (i) a fluoropolymer comprising at least one cure site monomer that comprises at least one cyano group; (ii) a cure system comprising a functionalized biphenyl-based compound and at least one of: a dioxime compound represented by the formula (I): HON═R1═NOH wherein R1 is chosen from an alkyl group having 1 to 10 carbon atoms and an aryl group having 1 to 10 carbon atoms; a monoamidine-based compound represented by formula (IV): wherein Y is chosen from a substituted or unsubstituted alkyl, aryl, or aralkyl group or an unsubstituted or substituted fully or partially halogenated alkyl, aryl, or aralkyl group having to 22 carbon atoms; R4 is chosen from a hydrogen atom or a substituted or unsubstituted lower alkyl group of 1 to 6 carbon atoms, or an amino group; R5 is independently chosen from hydrogen atom, a substituted or unsubstituted lower alkyl group of 1 to 6 carbon atoms, an amino group or an hydroxyl group; and/or a perfluoropolyether. Also included are additional related compositions and methods.