An apparatus for generating synthesis gas from waste organic materials that consists of a thermal reduction gasification reactor which is a rotary reactor having a drying and volatilizing zone for gasifying organic materials and a reformation zone for converting the gasified organic materials to synthesis gas. Solid waste organic material is fed to the reactor that heats the solid material to a temperature of about 600° C. to about 1000° C. The synthesis gas generated by the apparatus is substantially hydrogen and carbon monoxide. The apparatus is combined with an electrical generation system for making purified hydrogen and electricity. Alternatively, the synthesis gas can be used as a source for hydrogen. The synthesis gas is cleaned, the composition is shifted to enrich the content of hydrogen, and the hydrogen is isolated from the other gases that make up the synthesis gas. Alternatively, the synthesis gas can be fermented forming an organic alcohol and an organic acid.