发明申请
- 专利标题: Polymerization process using a mixed catalyst system
- 专利标题(中): 使用混合催化剂体系的聚合方法
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申请号: US12661849申请日: 2010-03-25
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公开(公告)号: US20100190936A1公开(公告)日: 2010-07-29
- 发明人: Peter Phung Minh Hoang , Victoria Ker , Bradley Funk
- 申请人: Peter Phung Minh Hoang , Victoria Ker , Bradley Funk
- 专利权人: NOVA Chemicals (International) S.A.
- 当前专利权人: NOVA Chemicals (International) S.A.
- 优先权: CA2,605,044 20071001; CAPCT/CA2008/001738 20080930
- 主分类号: C08F4/78
- IPC分类号: C08F4/78 ; B01J31/12
摘要:
Polyethylene is made by (co)polymerizing ethylene in a gas-phase reactor using a mixed catalyst system comprising a chromium catalyst supported on silica and a Group 4 transition metal catalyst, separately supported on silica. The Group 4 transition metal catalyst is defined by the formula shown, wherein M is a Group 4 metal, PI is a phosphinimide or ketimide ligand (shown), L is a monoanionic ligand which is a cyclopentadienyl or a bulky heteroatom type ligand, m is 1 or 2, n is 0 or 1, and p is an integer. The mixed catalyst system gives access to polyethylene having a broad or bimodal molecular weight distribution. In the copolymerization of ethylene, reversed or partially reversed comonomer distribution is achieved: the supported Group 4 component provides polymer segments having higher molecular weight and also higher comonomer incorporation than polymer segments produced at the supported chromium sites.
公开/授权文献
- US2574630A Coupler for toy cars and releasing means 公开/授权日:1951-11-13
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