发明申请
- 专利标题: FINE-PARTICLED POLYMER DISPERSIONS CONTAINING STARCH
- 专利标题(中): 包含淀粉的精细聚合物分散体
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申请号: US11994213申请日: 2006-06-23
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公开(公告)号: US20100236736A1公开(公告)日: 2010-09-23
- 发明人: Andreas Brockmeyer , Hildegard Stein , Roland Ettl
- 申请人: Andreas Brockmeyer , Hildegard Stein , Roland Ettl
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DE Ludwigshafen
- 优先权: DE102005030789.2 20050629
- 国际申请: PCT/EP06/63503 WO 20060623
- 主分类号: D21H17/28
- IPC分类号: D21H17/28 ; C08L3/02
摘要:
Finely divided, starch-containing polymer dispersions which are obtainable by free radical emulsion copolymerization of (a) from 25 to 50% by weight of at least one optionally substituted styrene, methyl methacrylate, acrylonitrile and/or methacrylonitrile, (b) from 1 to 49% by weight of at least one C1-C4-alkyl acrylate and/or one C2-C4-alkyl methacrylate, (c) from 1 to 49% by weight of at least one C5-C22-alkyl acrylate and/or one C5-C22-alkyl methacrylate and (d) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer and (e) from 15 to 40% by weight of a degradable starch which has a molar mass Mw of from 1000 to 65 000 the sum (a)+(b)+(c)+(d)+(e) being 100% and being based on the total solids content, in the presence of redox initiators and at least 0.01% by weight, based on the monomers used, of at least one polymerization regulator, processes for the preparation of the finely divided, starch-containing polymer dispersions by emulsion polymerization of the monomers (a), (b), (c) and (d) with redox initiators in the presence of (e) degraded starch and at least 0.01% by weight, based on the monomers used, of at least one polymerization regulator, and use of the finely divided, starch-containing polymer dispersions as sizes for paper, board and cardboard.
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