发明申请
- 专利标题: METHOD FOR CHANGING THE PREDEFINED MEAN MOLECULAR WEIGHT MN DURING THE CONTINUOUS PRODUCTION OF POLYTETRAHYDROFURANES OR THE COPOLYMERS
- 专利标题(中): 在连续生产聚四氢呋喃或共聚物期间改变预测的均分子量MN的方法
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申请号: US12295152申请日: 2007-12-10
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公开(公告)号: US20100240864A1公开(公告)日: 2010-09-23
- 发明人: Rolf Pinkos , Jochen Steiner , Stefan Käshammer , Tobias Wabnitz
- 申请人: Rolf Pinkos , Jochen Steiner , Stefan Käshammer , Tobias Wabnitz
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 优先权: EP07100828.8 20070119
- 国际申请: PCT/EP2007/063571 WO 20071210
- 主分类号: C08G65/20
- IPC分类号: C08G65/20
摘要:
The present invention provides a process for changing the given mean molecular weight Mn in the continuous preparation of polytetrahydrofuran or tetrahydrofuran copolymers, the mono- or diesters of polytetrahydrofuran or of tetrahydrofuran copolymers by polymerizing tetrahydrofuran in the presence of a telogen and/or of a comonomer over an acidic catalyst, wherein a) the molar ratio of telogen to tetrahydrofuran or to tetrahydrofuran and comonomer is changed, b) then the mean molecular weight of at least one sample is determined, c) until the mean molecular weight thus determined differs from the molecular weight to be achieved by the change, the already formed polytetrahydrofuran or the tetrahydrofuran copolymers, the mono- or diesters of polytetrahydrofuran or tetrahydrofuran copolymer is at least partly depolymerized over an acidic catalyst and d) the tetrahydrofuran recovered by depolymerization is recycled at least partly into the polymerization.
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