Disclosed are an electronic device enabling wireless networking through a wireless network and a network accessing method thereof, the electronic device including: a communicating unit which accesses the wireless network to perform wireless networking; an encoding unit which encodes a signal transmitted from or received by the communicating unit; and a controller which controls the encoding unit to encode identification information of the electronic device, in response to the electronic device being powered on, and controls the communicating unit to initiate an access to the wireless network based on the identification information encoded by the encoding unit. Accordingly, an automatic access to the wireless network is initiated when the electronic device is powered on, without any special manipulation by the user, thereby enhancing convenience to the user.