发明申请
- 专利标题: Dehydration of Alcohols on Crystalline Silicates
- 专利标题(中): 醇在结晶硅酸盐上的脱水
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申请号: US12864966申请日: 2009-02-05
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公开(公告)号: US20110124939A1公开(公告)日: 2011-05-26
- 发明人: Delphine Minoux , Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk , Jean-Pierre Dath
- 申请人: Delphine Minoux , Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk , Jean-Pierre Dath
- 申请人地址: BE Seneffe (Feluy)
- 专利权人: TOTAL PETROCHEMICALS RESEARCH FELUY
- 当前专利权人: TOTAL PETROCHEMICALS RESEARCH FELUY
- 当前专利权人地址: BE Seneffe (Feluy)
- 优先权: EP08151146.1 20080207; EP08154404.1 20080411
- 国际申请: PCT/EP09/51329 WO 20090205
- 主分类号: C07C1/24
- IPC分类号: C07C1/24
摘要:
The present invention relates to a process for the dehydration of at least an alcohol to make at least an olefin, comprising:introducing in a reactor a stream (A) comprising at least an alcohol, optionally water, optionally an inert component, contacting said stream with a catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, recovering from said reactor an olefin containing stream (B), Wherein the catalyst is: a crystalline silicate having a ratio Si/Al of at least about 100, or a dealuminated crystalline silicate, or a phosphorus modified zeolite, the WHSV of the alcohols is at least 2 h−1, the temperature ranges from 280° C. to 500° C. It relates also to the same process as above but wherein the catalyst is a phosphorus modified zeolite and at any WHSV.The partial pressure of the alcohol in the dehydration reactor advantageously ranges from 1.2 to 4 bars absolute (0.12 MPa to 0.4 MPa), the temperature of the dehydration reactor ranges advantageously from 300° C. to 400° C. and the alcohol is selected among ethanol, propanol, butanol and phenylethanol.
公开/授权文献
- US09061954B2 Dehydration of alcohols on crystalline silicates 公开/授权日:2015-06-23
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