发明申请
US20110137083A1 CONTINUOUS METHOD AND REACTOR FOR HYDROGENATING ORGANIC COMPOUNDS
审中-公开
氢化有机化合物的连续方法和反应器
- 专利标题: CONTINUOUS METHOD AND REACTOR FOR HYDROGENATING ORGANIC COMPOUNDS
- 专利标题(中): 氢化有机化合物的连续方法和反应器
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申请号: US12994575申请日: 2009-05-20
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公开(公告)号: US20110137083A1公开(公告)日: 2011-06-09
- 发明人: Joachim Pfeffinger
- 申请人: Joachim Pfeffinger
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 优先权: EP08156991.5 20080527
- 国际申请: PCT/EP09/56120 WO 20090520
- 主分类号: C07C211/35
- IPC分类号: C07C211/35 ; B01J19/26
摘要:
The present invention relates to a continuous process for hydrogenating organic compounds in a polyphasic system in the presence of a homogeneous or heterogeneous catalyst, which comprises performing the process in two stages, the first stage being performed in a loop reactor with an external heat exchanger and the second stage in a bubble column reactor with limited backmixing.The present invention further relates to a hydrogenation reactor (1) in a tall cylindrical design comprising a concentric guide tube (2) arranged in the lower reaction region and a mixing nozzle (3) directed upward, through which reactants and reaction mixture can be supplied, a pump (4) and a heat exchanger (5), which are present in an external pump circulation system which leads from the reactor to the mixing pump, and with one or more gas- and liquid-permeable internals (10) mounted in the upper region of the reactor, where the ratio of total length to diameter of the hydrogenation reactor (1) is in the range from 5:1 to 100:1 and the ratio of the volume of the upper region of the reactor to the volume of the lower region of the reactor is from 0.05:1 to 10:1.
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