Chemical reactors with annularly positioned delivery and removal devices, and associated systems and methods. A reactor in accordance with a particular embodiment includes a reactor vessel having a light-transmissible surface proximate to a reaction zone, and a movable reactant delivery system positioned within the reactor vessel. The reactor can further include a product removal system positioned within the reactor vessel and positioned annularly inwardly or outwardly from the delivery system. A solar concentrator is positioned to direct solar radiation through the light-transmissible surface to the reaction zone.