Invention Application
- Patent Title: Solid State Polymerization Process for Polyester with Phosphinic Acid Compounds
- Patent Title (中): 聚酯与膦酸化合物的固态聚合方法
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Application No.: US13214751Application Date: 2011-08-22
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Publication No.: US20110306710A1Publication Date: 2011-12-15
- Inventor: Paul Odorisio , Stephen M. Andrews , Thomas F. Thompson , Si Wu , Paragkumar Thanki , Deepak M. Rane , Delina Joseph , Jianzhao Wang
- Applicant: Paul Odorisio , Stephen M. Andrews , Thomas F. Thompson , Si Wu , Paragkumar Thanki , Deepak M. Rane , Delina Joseph , Jianzhao Wang
- Main IPC: C08K5/5313
- IPC: C08K5/5313 ; C08G63/86 ; C08G63/85 ; C08L67/02

Abstract:
Disclosed is a method for increasing the solid state polymerization (SSP) rates of metal catalyzed polyesters. The method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester and in a third step, further increasing the molecular weight and viscosity of the polyester under SSP conditions of a suitable temperature and pressure, where a metal catalyst is added in the first step or in the second step as a reaction catalyst, and where a certain phosphinic acid compound is added in the first step, in the second step or just prior to the third step. The polyester product exhibits low aldehyde formation during melt processing steps as well as excellent color.
Public/Granted literature
- US08258253B2 Solid state polymerization process for polyester with phosphinic acid compounds Public/Granted day:2012-09-04
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