发明申请
- 专利标题: Non-destructive process for the elimination of silicon from alumina based materials
- 专利标题(中): 从氧化铝基材料中消除硅的非破坏性工艺
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申请号: US13140310申请日: 2009-12-09
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公开(公告)号: US20120040822A1公开(公告)日: 2012-02-16
- 发明人: Patricia Pérez Romo , José Marie Maurice Julien Fripiat , Luis Miguel Rodríguez Otal , Pedro Martín Vega Merino , María de Lourdes Alejandra Guzmán Castillo , Candido Aguilar Barrera , Héctor Armendáriz Herrera , Francisco Javier Hernández Beltrán
- 申请人: Patricia Pérez Romo , José Marie Maurice Julien Fripiat , Luis Miguel Rodríguez Otal , Pedro Martín Vega Merino , María de Lourdes Alejandra Guzmán Castillo , Candido Aguilar Barrera , Héctor Armendáriz Herrera , Francisco Javier Hernández Beltrán
- 申请人地址: MX Mexico City
- 专利权人: INSTITUTO MEXICANO DEL PETROLEO
- 当前专利权人: INSTITUTO MEXICANO DEL PETROLEO
- 当前专利权人地址: MX Mexico City
- 优先权: MXMX/A/2008/016198 20081217
- 国际申请: PCT/MX2009/000133 WO 20091209
- 主分类号: B01J38/52
- IPC分类号: B01J38/52 ; B01J38/48
摘要:
The present invention refers to a method for eliminating silicon or silicon compounds that are contained in alumina based materials without destroying such alumina based materials allowing for their reutilization, its main application is being the regeneration of alumina based catalyst contaminated with silicon, which are used in hydro-treating processes in the oil industry for sulfur elimination and silicon removal from process streams. It is important to note that the procedures and/or conventional methods known so far for the elimination and removal of silicon contained in alumina based materials, use inorganic acids or their mixture in a digestion process which modifies the properties of alumina and of any other element contained in the material, thus destroying the alumina and disabling their reutilization. The non-destructive method of the present invention is characterized by the fact that an extraction agent depolymerize the silicon compounds deposited in alumina based materials, with no modification of the properties of the alumina based material and with no substantial modification of other materials o or on the metal content present in the alumina based material. The extraction agent used is an alcohol, preferably a polyol and more preferably glycerol, which is available needless of high grade of purity for its use. The silicon contained in alumina based materials, in which the non-destructive method of the present invention is used, is preferably found in inorganic structures such as oxide or silanol: Si—(OX)4(X═Al, H, Si) and/or as organosilanes structures: (OX)3—Si—CH3 and/or (CH3)2—Si—(OX)2(X═H, Si), both are depolymerized when this removal method is used.
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