There is provided a double window/door system for blocking infrared rays which includes a first glass member, a second glass member, and a spacer positioned between the first glass member and the second glass member for maintaining the space between the first glass member and the second glass member, characterized in that one of the surfaces of the first glass member is coated with a nano substance film for blocking near infrared rays and one of the surfaces of the second glass member is coated with a thermochromic substance film.