发明申请
- 专利标题: PROCESS FOR PREPARING ACRYLIC ACID FROM METHANOL AND ACETIC ACID
- 专利标题(中): 从甲醇和乙酸制备丙烯酸的方法
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申请号: US13233560申请日: 2011-09-15
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公开(公告)号: US20120071688A1公开(公告)日: 2012-03-22
- 发明人: Stefanie HERZOG , Stefan Altwasser , Klaus Joachim Mueller-Engel
- 申请人: Stefanie HERZOG , Stefan Altwasser , Klaus Joachim Mueller-Engel
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 优先权: DE102010040921.9 20100916
- 主分类号: C07C57/04
- IPC分类号: C07C57/04 ; C07C51/36
摘要:
A process for preparing acrylic acid from methanol and acetic acid, in which, in a reaction zone A, the methanol is partially oxidized to formaldehyde in a heterogeneously catalyzed gas phase reaction, the product gas mixture A obtained and an acetic acid source are used to obtain a reaction gas input mixture B which comprises acetic acid and formaldehyde and has the acetic acid in excess over the formaldehyde, and the formaldehyde present in reaction gas input mixture B is aldol-condensed to acrylic acid under heterogeneous catalysis in a reaction zone B with acetic acid present in reaction gas input mixture B, and unconverted acetic acid still present alongside the acrylic acid target product in the product gas mixture B obtained is removed therefrom, and the acetic acid removed is recycled into the production of reaction gas input mixture B.
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