A power switching device including a rectifier circuit and a control circuit is provided. A first terminal of the rectifier circuit receives an external voltage source and a second terminal of the rectifier circuit is electrically connected to a node. The control circuit is electrically connected between the node and a battery. Furthermore, during a power supply mode, the control circuit provides a power supply path, so that the battery provides a battery current to the node. Besides, the control circuit detects the battery current and determines whether or not to switch to a normal mode from the power supply mode according to the detection result.