发明申请
- 专利标题: Fibre-Reactive Azo Dyes, Their Preparation And Their Use
- 专利标题(中): 纤维反应偶氮染料及其制备及其应用
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申请号: US13384350申请日: 2010-06-30
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公开(公告)号: US20120117737A1公开(公告)日: 2012-05-17
- 发明人: Athanassios Tzikas , Herbert Klier , Georg Roentgen
- 申请人: Athanassios Tzikas , Herbert Klier , Georg Roentgen
- 申请人地址: CH Basel
- 专利权人: Huntsman Advanced Materials (Switzerland) GNBH
- 当前专利权人: Huntsman Advanced Materials (Switzerland) GNBH
- 当前专利权人地址: CH Basel
- 优先权: EP09167920.9 20090814
- 国际申请: PCT/EP10/59292 WO 20100630
- 主分类号: D06P1/38
- IPC分类号: D06P1/38 ; C09B43/00 ; C09B62/00 ; C09B31/14
摘要:
Reactive dyes of the formula (1) wherein B is an aliphatic bridging member, G is a sulfo naphthalene group or a sulfo benzene group of the formula (2a) or a pyridone radical of the formula (2b), R1, R2, R3 and R4 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, (R5)h denotes h identical or different substituents selected from the group sulfo, C1-C4alkyl and C1-C4alkoxy, R6 is hydrogen, sulfo, halogen, carboxy, C1-C4alkyl, C1-C4alkoxy or a fibre-reactive group Z1 of the formula —SO2—Y (3a), —NH—CO—(CH2)l—SO2—Y (3b), —CONH—(CH2)m—SO2—Y (3c), —NH—CO—CH(Hal)-CH2-Hal (3d) or —NH—CO—C(Hal)=CH2 (3e), R7 is amino, C1-C4alkyl or a fibre-reactive group Z2 of the formula —NH—(CH2)nSO2—Y (3a), (R8)j denotes j identical or different substituents selected from the group sulfo, C2-C4alkanoylamino, ureido, C1-C4alkyl and C1-C4alkoxy, R9 is hydrogen, C1-C4alkyl or C1-C4alkoxy, R10 is hydrogen or C1-C4alkyl, R11 is hydrogen, cyano, carbamoyl or sulfomethyl, and R12 is hydrogen, C1-C4alkyl, or phenyl which is unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, ureido, halogen or sulfo, X1 and X2 are halogen, Hal is chlorine or bromine, h and j are each independently of the other a number 0, 1 or 2; k is a number 1, 2 or 3; I, m and n are each independently of the other a number 2, 3 or 4, and Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, with the proviso that the dye of formula (1) contains at least one fibre-reactive group Z1 or Z2 are suitable for dyeing cellulosic or amide-group-containing fibre materials.
公开/授权文献
- US08562694B2 Fibre-reactive azo dyes, their preparation and their use 公开/授权日:2013-10-22
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