发明申请
US20120123169A1 PROCESS FOR PREPARING ALPHA,BETA-UNSATURATED C10-ALDEHYDES
有权
制备ALPHA,不饱和C10-醛缩合物的方法
- 专利标题: PROCESS FOR PREPARING ALPHA,BETA-UNSATURATED C10-ALDEHYDES
- 专利标题(中): 制备ALPHA,不饱和C10-醛缩合物的方法
-
申请号: US13256116申请日: 2010-02-23
-
公开(公告)号: US20120123169A1公开(公告)日: 2012-05-17
- 发明人: Alfred Kaizik , Dirk Fridag , Hans-Gerd Lueken , Wilfried Bueschken
- 申请人: Alfred Kaizik , Dirk Fridag , Hans-Gerd Lueken , Wilfried Bueschken
- 申请人地址: DE Marl
- 专利权人: Evonik Oxeno GmbH
- 当前专利权人: Evonik Oxeno GmbH
- 当前专利权人地址: DE Marl
- 优先权: DE102009001594.9 20090317
- 国际申请: PCT/EP2010/052271 WO 20100223
- 主分类号: C07C45/45
- IPC分类号: C07C45/45
摘要:
The invention relates to a method for continuously producing α,β-unsaturated C10-aldehydes from aliphatic C5-aldehydes, comprising the following steps: aldol-condensing aliphatic C5-aldehydes into α,β-unsaturated C10-aldehydes in the presence of an aqueous base in a tube reactor; phase separating the output of the tube reactor into an aqueous catalyst phase and an organic product phase; separating the organic product phase into α,β-unsaturated C10-aldehydes, aliphatic C5-aldehydes, and auxiliary products; discharging a part of the aqueous catalyst phase to remove the reaction water and supplementing said part with liquor solution and subsequently returning said part to the tube reactor. The task of the invention is to improve a method of said kind in a way such that it requires lower energy input. This is achieved in that the aliphatic C5-aldehydes and/or the α,β-unsaturated C10-aldehydes are dispersed in the aqueous base as drops, wherein the average Sauter diameter of the drops is between 0.2 mm and 2 mm.
公开/授权文献
- US08581008B2 Process for preparing α,β-unsaturated C10-aldehydes 公开/授权日:2013-11-12
信息查询