发明申请
- 专利标题: SILSESQUIOXANE PHOTOINITIATORS
- 专利标题(中): SILSESQUIOXANE照相机
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申请号: US13130796申请日: 2009-11-24
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公开(公告)号: US20120142793A1公开(公告)日: 2012-06-07
- 发明人: Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
- 申请人: Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
- 申请人地址: DE LUDWIGSHAFEN
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE LUDWIGSHAFEN
- 优先权: EP08170335.7 20081201
- 国际申请: PCT/EP2009/065695 WO 20091124
- 主分类号: C08F2/46
- IPC分类号: C08F2/46 ; C08G77/38 ; C08J9/00 ; C09D137/00 ; C09D11/10 ; C09J137/00 ; C08G77/388 ; C08F224/00
摘要:
Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1′) wherein n is 2m; m is an integer of 2 to 30; the sum of n′+a is an integer 4-60; n′ is an even-numbered integer; a is an even- or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.
公开/授权文献
- US08637585B2 Silsesquioxane photoinitiators 公开/授权日:2014-01-28