发明申请
US20120157709A1 PROCESS FOR PREPARATION AND PREFERABLY DISTILLATIVE WORKUP OF DIPHENYLMETHANE DIISOCYANATE (MDI)
有权
二氯甲烷二异氰酸酯(MDI)的制备和优选分离工艺
- 专利标题: PROCESS FOR PREPARATION AND PREFERABLY DISTILLATIVE WORKUP OF DIPHENYLMETHANE DIISOCYANATE (MDI)
- 专利标题(中): 二氯甲烷二异氰酸酯(MDI)的制备和优选分离工艺
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申请号: US13393088申请日: 2010-10-20
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公开(公告)号: US20120157709A1公开(公告)日: 2012-06-21
- 发明人: Christian Schneider , Nikolaus Zafred , Andreas Heussler , Leo Denissen , Lucia Koenigsmann
- 申请人: Christian Schneider , Nikolaus Zafred , Andreas Heussler , Leo Denissen , Lucia Koenigsmann
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 优先权: EP09173515.9 20091020
- 国际申请: PCT/EP2010/065782 WO 20101020
- 主分类号: C07C263/10
- IPC分类号: C07C263/10
摘要:
What is proposed is a process for preparation and distillative workup of diphenylmethane diisocyanate (MDI), proceeding from a benzene-comprising feedstream, in which, in a catalytic hydrogenation of nitrobenzene to aniline, steam is raised at two different pressure levels, which partly or completely covers the energy demand for the overall process, by using two fluidized bed reactors of identical design, of which a first fluidized bed reactor is operated with an aniline load for which the fluidized bed reactors have been designed and provides steam at a first, lower pressure level, and a second fluidized bed reactor is operated with a load lowered with respect to the first fluidized bed reactor to such an extent that the second fluidized bed reactor affords steam at the higher pressure level.
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