发明申请
US20120165544A1 Process for Preparing 1-Phenylpyrazoles 有权
制备1-苯基吡唑的方法

  • 专利标题: Process for Preparing 1-Phenylpyrazoles
  • 专利标题(中): 制备1-苯基吡唑的方法
  • 申请号: US13393624
    申请日: 2010-09-03
  • 公开(公告)号: US20120165544A1
    公开(公告)日: 2012-06-28
  • 发明人: Maximilian DochnahlGunter Lipowsky
  • 申请人: Maximilian DochnahlGunter Lipowsky
  • 申请人地址: DE Ludwigshafen
  • 专利权人: BASF SE
  • 当前专利权人: BASF SE
  • 当前专利权人地址: DE Ludwigshafen
  • 优先权: EP09169528.8 20090904
  • 国际申请: PCT/EP10/62950 WO 20100903
  • 主分类号: C07D231/22
  • IPC分类号: C07D231/22 C07D231/20
Process for Preparing 1-Phenylpyrazoles
摘要:
The present invention to a process for preparing 1-phenylpyrazoles of the formula I in which each R1 is independently selected from chlorine, fluorine, alkyl, haloalkyl, alkoxy and haloalkoxy; n is 1, 2 or 3; each R2 is independently selected from cyano, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio and alkoxycarbonyl; m is 0, 1 or 2; A is alkyl, aryl or aryl-C1-C4-alkyl, where A optionally bears 1, 2, 3 or 4 substituents comprising reacting a phenyl halide of the formula (II) with apyrazole derivative of the formula (III) in which X is chlorine, iodine or bromine; and R1, n, R2, m and A are each as defined above, in the presence of a base and a catalytic system comprising a ligand and a metal compound selected from palladium compounds, iron compounds and copper compounds.
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