A duplex stainless steel excellent in the weldability during large heat input welding and in the stress corrosion cracking resistance in a chloride environment containing corrosive associated gases has a chemical composition consisting, by mass %, of C: 0.03% or less, Si: 0.2 to 1%, Mn: 5.0% or less, P: 0.040% or less, S: 0.010% or less, sol. Al: 0.040% or less, Ni: 4 to 8%, Cr: 20 to 28%, Mo: 0.5 to 2.0%, Cu: more than 2.0% and 4.0% or less and N: 0.1 to 0.35%, and optionally contains one or more selected from among V, Ca, Mg, B and a rare earth metal(s), with the balance being Fe and impurities; wherein the duplex stainless steel satisfies the following formulas: 2.2Cr+7Mo+3Cu>66   (1) Cr+11Mo+10Ni